Кулик Леонид Викторович

 

Профессор РАН, доктор физико-математических наук


Образование:

1999 магистр физики, Новосибирский Государственный Университет, кафедра химической и биологической физики;

2003 Кандидат физико-математических наук, тема диссертации «Исследование структуры и динамики фотосинтетических и модельных радикальных пар методом электронного спинового эхо», научный руководитель – д. ф.-м. н., проф. Дзюба С. А.;

2010 Доктор физико-математических наук, тема диссертации «Новые методы спектроскопии электронного спинового эхо и их применение для исследования структуры и динамики нитроксильных спиновых меток и биологических систем»;

2016 Профессор РАН, Отделение химии.


Должность:

Руководитель группы Органической Фотовольтаики, входящей в Лабораторию Химии и физики свободных радикалов ИХГК СО РАН.

Тематики группы:

  • фотовозбуждение, перенос энергии и заряда в композитах полупроводящих полимеров, фуллеренов и нефуллереновых акцепторов – современных материалах активного слоя фотовольтаических ячеек (исследование магнитно-резонансными, оптическими и фотоэлектрическими методами);
  • синтез и применения добавок, модифицирующих морфологию активного слоя фотовольтаических ячейках, в том числе функционализованных углеродных нанотрубок;
  • изучение механизмов деградации фотовольтаических ячейках и разработка способов предотвращения этой деградации.


Международное научное сотрудничество:

В 2001 – 2003 гг. Леонид Кулик совершил несколько визитов Лейденский университет (Нидерланды), где изучал индуцированное светом разделение зарядов в фотосинтезирующих бактериальных реакционных центрах.

В период с октября 2003 г. по март 2005 г. Леонид Кулик работал в группе профессора доктора В. Любица в Институте бионеорганической химии им. Макса Планка, Мюльхайм-ан-дер-Рур, Германия, в рамках исследовательской стипендии, присуждаемой Фондом Александра фон Гумбольдта. Работа касалась импульсного ЭПР и ДЭЯР (электронно-ядерного двойного резонанса) исследования кислород-выделяющего комплекса фотосистемы II растений.

В 2015 - 2017 годах был осуществлен проект сотрудничества между научными группами Института химической кинетики и горения СО РАН (Новосибирск, Россия) Института химико-химического преобразования энергии Общества Макса Планка (Мюльхейм-ан-дер-Рур, Германия) «Светоиндуцированные процессы и парамагнитных частиц в органической фотовольтаике и фотосинтезе». Этот проект финансировался Фондом Александра фон Гумбольдта (Alexander von Humboldt Foundation). Леонид Кулик выступил координатором проекта с российской стороны.


Награды:

2004 медаль Российской Академии Наук для молодых ученых

2007 медаль Международного Общества ЭПР (International EPR Society) для молодых ученых


Научная и организационная работа:

С 2015 – член международного комитета по спиновой химии и программного комитета регулярной международной конференции Spin Chemistry Meeting.

2016 – 2019 Заместитель председателя диссертационного совета Д.003.014.02 при ИХКГ СО РАН (Химическая физика, горение и взрыв, физика экстремальных состояний вещества).

С 2016 – эксперт РАН, член Объединенного ученого совета Cибирского отделения РАН по химическим наукам.

2018 – председатель оргкомитета Школы молодых ученых «Магнитный резонанс и магнитные явления в химической и биологической физике», 15 — 20 сентября 2018, пос. Рощино Ленинградской области.

2019 – сопредседатель оргкомитета 16-ой Конференция по Спиновым и магнитным эффектам в химии (Spin Chemistry Meeting 2019), Санкт-Петербург 18-22 августа 2019.


Рецензент в журналах:

JACS, J. Chem. Phys. Lett., J. Chem. Phys. B and C, J. Phys. Chem., Appl. Magn. Res., ACS Applied Materials and Interfaces, Molecules, Chinese Journal of Chemistry, PCCP, Photosynthesis Research, New Journal of Chemistry.

 

Публикации:

1. Tsentalovich Y.P., Kulik L.V., Gritsan N.P., Yurkovskaya A.V. (1998) Solvent effect on the rate of beta-scission of the tert-butoxyl radical, J. Phys. Chem. A, 102, 7975-7980.

2. Borovykh I.V., Kulik L.V., Dzuba S.A., Hoff A.J. (2001) Selective excitation in pulsed EPR of spin-correlated radical pairs: electron-electron interactions, zero-, single-, and double-quantum relaxation and spectral diffusion, Chem. Phys. Lett., 338, 173-179.

3. Kulik L.V., Dzuba S.A., Grigoryev I.A., Tsvetkov Y.D. (2001) Electron dipole-dipole interaction in ESEEM of nitroxide biradicals, Chem. Phys. Lett., 343, 315-324.

4. Kulik L.V., Grishin Y.A., Dzuba S.A., Grigoryev I.A., Klyatskaya S.V., Vasilevsky S.F., Tsvetkov Y.D. (2002) Electron dipole-dipole ESEEM in field-step ELDOR of nitroxide biradicals, J. Magn. Res., 157, 61 - 68.

5. Kulik L. V., Dzuba S. A. (2002) Electron dipole-dipole interaction in ESEEM of biradicals, in “EPR in the 21st century: basics and applications to material, life and earth sciences”, Eds Kawamori A., Yamaguchi J., Ohta H., (Elsevier), ISBN 0 444 509739, 669 – 677.

6. Borovykh I.V., Kulik L.V., Dzuba S.A., Hoff A.J. (2002) Out-of-phase stimulated ESE appearing in the evolution of spin-correlated photosynthetic triplet-radical pairs, J. Phys. Chem. B, 106, 12066 – 12071.

7. Kulik L. V., Paschenko S. V., Dzuba S. A. (2002) 130 GHz ESEEM induced by electron-electron interaction in biradical, J. Magn. Res., 159, 237 – 241.

8. Kulik L.V., Igor A. Grigor’ev, Salnikov E. S., Dzuba S. A., Tsvetkov Yu. D. (2003) Electron Spin-Echo Envelope Modulation Induced by Slow Intramolecular Motion, J. Phys. Chem. A, 107, 3692 – 3695.

9. Kulik L.V., Borovykh I.V., Gast P., Dzuba S.A. (2003) Selective excitation in pulsed EPR of spin-correlated triplet-radical pair, J. Magn. Res., 162, 423 – 428.

10. Borovykh I.V., Kulik L.V, Gast P., Dzuba S.A. (2003) Conformation transition in the protein of a photosynthetic reaction center observed at the nanometer range of distances at cryogenic temperatures, Chem. Phys., 294, 433 – 438.

11. Kulik L. V., Dzyuba S. A. (2004) Electron spin echo study of molecular structure and dynamics: New approaches based on spontaneous fluctuations of magnetic interactions, J. Struct. Chem., 45, 298 – 314. Кулик Л. В., Дзюба С. А. (2004) Изучение структуры и динамики молекул в электронном спиновом эхо: новые подходы, основанные на спонтанных флюктуациях магнитных взаимодействий, Журнал Структурной Химии, 45, 314 – 330.

12. Kulik L.V., Salnikov E. S., Dzuba S. A. (2005) Nuclear spin relaxation in free radicals as revealed in a stimulated electron spin echo experiment, Appl. Magn. Res., 28, 1-11.

13. Kulik L. V., Epel B., Messinger J., Lubitz W. (2005) Pulse EPR, 55Mn-ENDOR and ELDOR-detected NMR of the S2-state of the Oxygen Evolving Complex in Photosystem II, Photosynthesis Res., 84, 347 - 353.

14. Kulik L. V., Epel B., Lubitz W., Messinger J. (2005) 55Mn Pulse ENDOR at 34 GHz of the S0- and S2-States of the Oxygen Evolving Complex in Photosystem II., J. Am. Chem. Soc., 127, 2392 - 2393.

15. Kulik L. V., Lubitz W., Messinger J. (2005) Electron Spin-Lattice Relaxation of the S0 State of the Oxygen-Evolving Complex in Photosystem II and of Dinuclear Manganese Model Complexes, Biochemistry 44, 9368 – 9374.

16. Dzuba S.A., Kirilina E.P., Salnikov E.S., Kulik L.V. (2005) Restricted orientational motion of nitroxides in molecular glasses: Direct estimation of the motional time scale basing on the comparative study of primary and stimulated electron spin echo decays, J. Chem. Phys. 122, 94702 – 94709.

17. Dzuba S. A., Salnikov E.S., Kulik L.V. (2006) CW EPR, Echo-Detected EPR, and Field-Step ELDOR study of Molecular Motions of Nitroxides in o-Terphenyl Glass: Dynamical Transition, Dynamical Heterogeneity and -relaxation, Appl. Magn. Res. 30, 637 – 650.

18. Уваров М. Н., Кулик Л. В. (2007) Изучение спиновой динамики триплетного фуллерена С60 в стеклообразном орто-терфениле методом электронного спинового эхо, Вестник НГУ. Серия: физика. 2, 21 – 25.

19. Kulik L. V., Epel B., Lubitz W., Messinger J. (2007) Electronic Structure of the Mn4OxCa Cluster in the S0 and S2 States of the Oxygen-Evolving Complex of Photosystem II Based on Pulse 55Mn-ENDOR and EPR Spectroscopy, J. Am. Chem. Soc., 129, 13421 - 13435.

20. Messinger J., Kulik L. V., Epel B., Zein S., Yano J. (2007) Electronic Structure of the Mn4OxCa Cluster in the S0 and S2 States of the Oxygen-Evolving Complex of Photosystem II Based on Pulse EPR, Photosynthesis Res., 91, 173 - 174.

21. Uvarov M. N., Kulik L. V., Bizin M. A., Ivanova V. N., Zaripov R. B., Dzuba S. A. (2008) Anisotropic Pseudorotation of the Photoexcited Triplet State of Fullerene C60 in Molecular Glasses Studied by Pulse EPR, J. Phys. Chem. A, 112, 2519 - 2525.

22. Zein S., Kulik L. V., Yano J., Kern J., Pushkar Y., Zouni A., Yachandra V. K., Lubitz W., Neese F., Messinger J. (2008) Focussing the view on Nature’s water-splitting catalyst, Phil. Trans. Royal Soc. B, 363, 1167 – 1177.

23. Messinger J., Kulik L. V., Lubitz W. (2009) Light-induced water-splitting in nature: Electronic structure of the manganese cluster in photosystem II, in Electron Paramagnetic Resonance Spectroscopy: From Fundamental Research to Pioneering Applications & Zavoisky Award, ed. Salikhov K. M., AXAS Publishing Ltd, New Zeeland, ISBN 978-1-877524-01-1, p. 164-165.

24. Ivanova N. A., Onischuk A. A., Vosel S. V., Purtov P. A., Kulik L. V., Rapatskiy L. L., Vasenin N. T., Anufrienko V. F. (2009) EPR spectra of aerosol particles formed by pyrolysis of C3H8 plus Ar and C3H8 plus Fe(CO)5 plus Ar mixtures in a flow reactor, Appl. Magn. Res. 35, 625-637.

25. Bogachev A. V, Kulik L. V., Bloch D. A., Bertsova Yu. V., Fadeeva M. S., Verkhovsky M. I. (2009) Redox Properties of the Prosthetic Groups of Na+-Translocating NADH:Quinone Oxidoreductase. 1. Electron Paramagnetic Resonance Study of the Enzyme, Biochemistry, 48, 6291–6298.

26. Bagryanskaya E. G., Polovyanenko D. N., Fedin M. V., Kulik L., Schnegg A., Savitsky A., Mobius K., Coleman A. W., Ananchenko G. S., Ripmeester J. A. (2009) Multifrequency EPR study of the mobility of nitroxides in solid-state calixarene nanocapsules, Phys. Chem. Chem. Phys., 11, 6700-6707.

27. Kulik L. V., Rapatsky L. L., Pivtsov A. V., Surovtsev N. V., Adichtchev S. V., Grigor’ev I. A., Dzuba S. A. (2009) Electron-nuclear double resonance study of molecular librations of nitroxides in molecular glasses: Quantum effects at low temperatures, comparison with low-frequency Raman scattering, J. Chem. Phys. 131, 064505-1 - 064505-6.

28. Uvarov M. N., Kulik L. V., Dzuba S. A. (2009) Spin relaxation of fullerene C70 photoexcited triplet in molecular glasses: Evidence for onset of fast orientational motions of molecules in the matrix near 100 K, J. Chem. Phys. 131, 144501-1 - 144501-4.

29. Kulik L. V., Lubitz W. (2009) Electron-nuclear double resonance, Photosynthesis Res., 102, 391 – 401.

30. Kulik L. V., Pivtsov A. V., Bogachev A. V. (2010) Pulse EPR, ENDOR, and ELDOR Study of Anionic Flavin Radicals in Na+-Translocating NADH:Quinone Oxidoreductase, Appl. Magn. Res. 37, 353 – 361.

31. Zinovieva A. F., Dvurechenskii A. V., Stepina N. P., Nikiforov A. I., Lyubin A. S., Kulik L. V. (2010) Direct measurements of spin relaxation times of electrons in tunnel-coupled Ge/Si quantum dot arrays, Phys. Rev. B 81, 113303-1 - 113303-4.

32. Isaev N. P., Kulik L. V., Kirilyuk I. A., Reznikov V. A., Grigor’ev I. A., Dzuba S. A. (2010) Fast stochastic librations and slow small-angle rotations of molecules in glasses observed on nitroxide spin probes by stimulated electron spin echo spectroscopy, J. Non-Cryst. Solids, 356, 1037–1042.

33. Машковцев Р. И., Кулик Л. В., Солнцев В. П. (2010) Атомы серебра в структурных каналах берилла, Журнал Структурной Химии 51, 897 – 903; Mashkovtsev R. I., Kulik L. V., Solntsev V. P. (2010) Silver atoms in the structural channels of beryl, Journal of Structural Chemistry, 51, 869-874.

34. Zaripov R. B., Dzhabarov V. I., Knyazev A. A., Galyametdinov Yu. G., Kulik L. V. (2011) Use of Additional Fast-Relaxing Paramagnetic Species for Improvement of RIDME Performance, Appl. Magn. Res., 40, 11 – 19.

35. Pivtsov A. V., Kulik L. V., Makarov A. Yu., Blockhuis F. (2011) Pulse EPR and ENDOR study of 1,2,3-benzodithiazolyl, 2,1,3-benzothiaselenazolyl and 1,2,3-benzodiselenazolyl radicals, Phys. Chem. Chem. Phys., 13, 3873 – 3880.

36. Cox N., Rapatskiy L., Su J.-H., Pantazis D. A., Sugiura M., Kulik L., Dorlet P., Rutherford A. W., Neese F., Boussac A., Lubitz W., Messinger J. (2011) Effect of Ca2+/Sr2+ Substitution on the Electronic Structure of the Oxygen-Evolving Complex of Photosystem II: A Combined Multifrequency EPR, 55Mn-ENDOR, and DFT Study of the S2 State, J. Am. Chem. Soc., 133, 3635–3648.

37. Uvarov M. N., Kulik L. V., Pichugina T. I., Dzuba S. A. (2011) Effects of spin transitions degeneracy in pulsed EPR of the fullerene C70 triplet state produced by continuous light illumination, Spectrochimica Acta A 78, 1548–1552.

38. Su J.-H., Cox N., Ames W., Pantazis D. A., Rapatskiy L., Lohmiller T., Kulik L. V., Dorlet P., Sugiura M., Rutherford A. W., Neese F., Boussac A., Lubitz W., Messinger J. (2011) The electronic structures of the S2 states of the oxygen-evolving complexes of photosystem II in plants and cyanobacteria in the presence and absence of methanol, Biochim. Biophys. Acta-Bioenergetics 1807, 829 – 840.

39. Uvarov M. N., Kulik L. V., Doktorov A. B., Dzuba S. A. (2011) Isotropic reorientations of fullerene C70 triplet molecules in solid glassy matrices revealed by light-induced electron paramagnetic resonance, J. Chem. Phys. 135, 054507-1 - 054507-7.

40. Cox N., Ames W., Epel B., Kulik L. V., Rapatskiy L., Neese F., Messinger J., Wieghardt K., Lubitz W. (2011) Electronic Structure of a Weakly Antiferromagnetically Coupled MnIIMnIII Model Relevant to Manganese Proteins: A Combined EPR, 55Mn-ENDOR, and DFT Study, Inorg. Chem., 50, 8238–8251.

41. Uvarov M. N., Kulik L. V., Dzuba S. A. (2011) Fullerene C70 Triplet Zero-Field Splitting Parameters Revisited by Light-Induced EPR at Thermal Equilibrium, Appl. Magn. Res., 40, 489 – 499.

42. Pivtsov A. V., Kulik L. V., Surovtsev N. V., Adichtchev S. V., Kirilyuk I. A., Grigor’ev I. A., Fedin M. V., Dzuba S. A. (2011) Temperature Dependence of Hyperfine Interaction for 15N Nitroxide in a Glassy Matrix at 10–210 K, Appl. Magn. Res., 41, 411 - 429.

43. Cox N., Rapatskiy L., Su J.-H., Pantazis D. A., Sugiura M., Kulik L., Dorlet P., Rutherford A. W., Neese F., Boussac A., Lubitz W., Messinger J. (2011) Effect of Ca2+/Sr2+ Substitution on the Electronic Structure of the Oxygen-Evolving Complex of Photosystem II: A Combined Multifrequency EPR, 55Mn-ENDOR, and DFT Study of the S2 State (vol. 133, pg. 3635, 2011), J. Am. Chem. Soc., 133, 14149–14149.

44. Verkhovsky M. I., Bogachev A. V., Pivtsov A. V., Bertsova Yu. V., Fedin M. V., Bloch D. A., Kulik L. V. (2012) Sodium-Dependent Movement of Covalently Bound FMN Residue(s) in Na+-Translocating NADH:Quinone Oxidoreductase, Biochemistry, 51, 5414–5421.

45. Nasibulov E. A., Kulik L. V., Kaptein R., Ivanov K. L. (2012) Theory of pulsed reaction yield detected magnetic resonance, Phys. Chem. Chem. Phys., 14, 13325-13331.

46. Л. В. Кулик (2012) Как “устроен” фотосинтез?, «Наука из первых рук», 1(43), 43 – 45.

47. Uvarov M. N., Kulik L. V. (2013) Electron Spin Echo of Photoinduced Spin-Correlated Polaron Pairs in P3HT:PCBM Composite, Appl. Magn. Res., 44, 97 – 106.

48. Konov K. B., Knyazev A. A., Galyametdinov Yu. G., Isaev N. P., Kulik L. V. (2013) Selective Hole-Burning in RIDME Experiment: Dead-Time Free Measurement of Dipolar Modulation, Appl. Magn. Res., 44, 949 – 966.

49. Zinovieva A. F., Nikiforov A. I., Timofeev V. A., Nenashev A. V., Dvurechenskii A. V., Kulik L. V. (2013) Electron localization in Ge/Si heterostructures with double quantum dots detected by an electron spin resonance method, Phys. Rev. B 88, 235308-1 - 113303-8.

50. Zinovieva A. F., Stepina N.P., Nikiforov A. I., Nenashev A. V., Dvurechenskii A. V., Kulik L.V., Carmo M. C., Sobolev N. A. (2014) Spin relaxation in inhomogeneous quantum dot arrays studied by electron spin resonance, Phys. Rev. B 89, 045305-1 – 045305-8.

51. Lukina E. A., Uvarov M. N., Kulik L.V. (2014) Charge Recombination in P3HT/PC70BM Composite Studied by Light-Induced EPR, J. Phys. Chem. C 118, 18307−18314.

52. Уваров М. Н., Попов А. Г., Лукина Е. А., Кулик Л. В. (2014) Спиновая релаксация и структура спин-коррелированных радикальных пар P3HT+/PCBM-, Журнал Структурной Химии 55, 679 – 685; Uvarov M. N., Popov A. G., Lukina E. A., Kulik L. V. (2014) Spin relaxation and structure of light-induced spin-correlated PCBM−/P3HT+ radical pairs, J. Struct. Chem. 55, 644-650.

53. Baranov D. S., Popov A. G., Uvarov M. N., Kulik L. V. (2014) Synthesis of benzo[de]isoquino[1,8-gh]quinolines and light-induced electron transfer in their composites with conductive polymer poly(3-hexylthiophene), Mendeleev Commun., 24, 383-385.

54. Baranov D. S., Popov A. G., Uvarov M. N., Kazantsev M. S., Mostovich E. A., Glebov E. M., Kulik L. V. (2015) Naphtho[4,3,2,1-lmn][2,9]phenanthrolines: Synthesis, characterization, optical properties and light-induced electron transfer in composites with the semiconducting polymer MEH-PPV, Synth. Met., 201, 43 – 48.

55. Zinovieva A., Stepina N., Dvurechenskii A., Kulik L., Mussler G., Moers J., Grützmacher D. (2015) Simultaneous Localization of Electrons in different ∆-valleys in Ge/Si Quantum Dot Structures, Solid State Phenomena, v. 233 – 234, pp. 415 – 418.

56. Stepina N. P., Zinovieva A. F., Zinoviev V. A., Deryabin A. S., Kulik L. V., Dvurechenskii A. V. (2015) Electron localization in self-assembled Si quantum dots grown on Ge(111), Semiconductor Science and Technology, 30, 125013.

57. Lukina E. A., Pozdnyakov I. P., Mereshchenko A. S., Uvarov M. N., Kulik L. V. (2015) Photochemistry of P3HT and PC60BM in Toluene Solution: Evidence of T-T Energy Transfer, J. Photochem. Photobiol. A: Chem. 311, 193–198.

58. Zinovieva A. F., Smagina Z. V., Nenashev A. V., Kulik L. V., Dvurechenskii A. V. (2015) Unusual narrowing of the ESR line width in ordered structures with linear chains of Ge/Si quantum dots, JETP Letters 102, 108 – 112.

59. Lukina E. A., Popov A. A., Uvarov M. N., Kulik L. V. (2015) Out-of-Phase Electron Spin Eсho Studies of Light-Induсed Charge-Transfer States in P3HT/PCBM Composite, J. Phys. Chem. B 119, 13543–13548.

60. Uvarov M. N., Behrends J., Kulik L. V. (2015) Higher triplet state of fullerene C70 revealed by electron spin relaxation, J. Chem. Phys. 143, 244314-1 - 244314-7.

61. Uvarov M. N. Behrends J., Maryasov A. G., Kulik L. V. (2016) Origin of the Puzzling Narrow Line in the EPR Spectrum of Triplet C70, Appl. Magn. Res. 47, 781-791.

62. Lukina E. A., Popov A. A., Uvarov M. N., Suturina E. A., Reijerse E. J., Kulik L. V. (2016) Light-induced charge separation in a P3HT/PC70BM composite as studied by out-of-phase electron spin echo spectroscopy, Phys. Chem. Chem. Phys., 18, 28585-28593.

63. Zinovieva A. F., Zinovyev V. A., Nenashev A. V., Kulik L. V., Dvurechenskii A. V. (2017) ESR Study of Electron States in Ge/Si Heterostructures with Nanodisc Shaped Quantum Dots, Zeitschrift für Physikalische Chemie, 231, 405–423.

64. Shatrova A. A., Baranov D. S., Uvarov M. N., Kazantsev M. S., Glebov E. M., Fadeev D. S., Kulik L. V. (2017) Novel Anthrathiophene-Based Small Molecules as Donor Material for Organic Photovoltaics: Synthesis and Light-Induced EPR Study, Zeitschrift für Physikalische Chemie, 231, 425–438.

65. Nasibulov E. A., Behrends J., Kulik L. V., Ivanov K. L. (2017) Theoretical Description of Pulsed RYDMR: Refocusing Zero-Quantum and Single Quantum Coherences, Zeitschrift für Physikalische Chemie, 231, 269–291.

66. Baranov D. S., Uvarov M. N., Kazantsev M. S., Mostovich E. A., Glebov E. M., Gatilov Y. V., Kulik L. V. (2017) Diaza-analogs of benzopyrene and perylene containing thienyl and 4-(phenylamino)phenyl groups: Synthesis, characterization, optical and electrochemical properties, Dyes and Pigments, 136, 707-714.

67. Popov A. A., Lukina E. A., Rapatskiy L, Kulik L. V. (2017) Time-domain shape of electron spin echo signal of spin-correlated radical pairs in polymer/fullerene blends, J. Magn. Res. 276, 86–94.

68. Nenashev A. V., Wiemer M., Dvurechenskii A. V., Kulik L. V., Pevtsov A. B., Gebhard F., Koch M., Baranovskii S. D. (2017) Analytical theory for charge carrier recombination in blend organic solar cells, Phys. Rev. B 95, 104207

69. Lukina E. A., Suturina E. A., Reijerse E. J., Lubitz W., Kulik L. V. (2017) Spin dynamics of light-induced charge separation in composites of semiconducting polymers and PC60BM revealed using Q-band pulse EPR, Phys. Chem. Chem. Phys., 19, 22141-22152

70. Baranov D. S., Uvarov M. N., Glebov E. M., Nevostruev D. A., Kazantsev M. S., Mostovich E. A., Fadeev D. S., Antonova O. V., Utkin D. E., Kuchinskaya P. A., Sukhikh A. S., Gromilov S. A., Kulik L. V. (2018) 1,3,7,9-Tetraazaperylene frameworks: Synthesis, photoluminescence properties, and thin film morphology, Dyes and Pigments, 150, 252-260.

71. Kulik L. V., Bertsova Y. V., Bogachev A. V. (2018) EPR evidence for a fast-relaxing iron center in Na+-translocating NADH:quinone-oxidoreductase, J. Biol. Inorg. Chem., 184, 15 – 18.

72. Baranov D. S., Uvarov M. N., Kazantsev M. S., Glebov E. M., Nevostruev D. A., Mostovich E. A., Antonova O. V., Kulik L. V. (2018) A Concise and Efficient Route to Electron-Accepting 2,2′-[2,2′-Arenediylbis(11-oxoanthra[1,2-b]thiophene-6-ylidene)]dipropanedinitriles. Eur. J. Org. Chem., 19, 2259–2266.

73. Lukina E. A., Reijerse E. J., Lubitz W., Kulik L. V. (2019) Spin-dependent recombination of the charge-transfer state in photovoltaic polymer/fullerene blends, Mol. Phys. 117, 2654-2663.

74. Zinovieva A. F., Zinovyev V. A., Nenashev A. V., Kulik L. V., Dvurechenskii A. V. (2019) Electron spatial localization tuned by strain in Ge/Si quantum dot heterostructures, Phys. Rev. B 99, 115314.

75. Baranov D. S., Krivenko O. L., Kazantsev M. S., Nevostruev D. A., Kobeleva E. S., Zinoviev V. A., Dmitriev A. A., Gritsan N. P., Kulik L. V. (2019) Synthesis of 2,2′-[2,2′-(arenediyl)bis(anthra[2,3-b]thiophene-5,10-diylidene)]tetrapropanedinitriles and their performance as non-fullerene acceptors in organic photovoltaics, Synth. Met. 255, 116097.

76. Uvarov M. N., Kulik L. V. (2019) Charge Transfer State in the Composite DTS(FBTTh2)2:PC71BM: Dynamics of Electron-Hole Distance Distribution After Light Absorption, Appl. Magn. Res. 50, 1277-1290.

77. Baranov D. S., Krivenko O. L., Nevostruev D. A., Glebov E. M., Uvarov M. N., Kazantsev M. S., Mostovich E. A., Kulik L. V. (2019) 2,7-Disubstituted 1,3,6,8-tetraazabenzopyrenes: Synthesis, characterization, optical and electrochemical properties, Dyes and Pigments 168, 219-227.

78. Zinovieva A. F., Zinovyev V. A., Stepina N. P., Katsuba A. V., Dvurechenskii A. V., Gutakovskii, A. K., Kulik L. V., Bogomyakov A. S., Erenburg S. B., Trubina S. V., Voelskow M. (2019) Electron Paramagnetic Resonance in Ge/Si Heterostructures with Mn-Doped Quantum Dots, JETP Lett. 109, 270-275.

79. Bertsova Y. V., Kulik L. V., Mamedov M. D., Baykov A. A., Bogachev A. V. (2019) Flavodoxin with an air-stable flavin semiquinone in a green sulfur bacterium, Photosynth. Res. 142, 127–136.

80. Ptushenko V. V., Solovchenko A. E., Bychkov A. Y., Chivkunova O. B., Golovin A. V., Gorelova O. A., Ismagulova T. T., Kulik L. V., Lobakova E. S., Lukyanov A. A., Samoilova R. I., Scherbakov P. N., Selyakh I. O., Semenova L. R., Vasilieva S. G., Baulina O. I., Skulachev M. V., Kirpichnikov M. P (2019) Cationic penetrating antioxidants switch off Mn cluster of photosystem II in situ, Photosynth. Res. 142, 229 – 240.

81. Beletskaya E. A., Lukina E. A., Uvarov M. N., Popov A. A., Kulik L. V. (2020) Geminate recombination in organic photovoltaic blend PCDTBT/PC71BM studied by out-of-phase electron spin echo spectroscopy, J. Chem. Phys. 152, 044706.

82. Kobeleva E.S., Nevostruev D.A., Krivenko O.L., Uvarov M.N., Gurova O.A., Lobiak E.V., Berezin A.S., Zinovyev V.A., Utkin D.E., Degtyarenko K.M., Kulik L.V. (2020) Charge Photogeneration in Composites of Fluorinated Carbon Nanotubes and Semiconducting Polymer P3HT, Physica Status Solidi B - Basic Solid State Physics 257, 2000161.

83. Nevostruev D.A., Baranov D. S., Zinovyev V.A., Sukhikh A. S., Kulik L.V. (2020) Photovoltaic Properties of Electron-Accepting 2,2'-[2,2'-Arenediylbis(11-oxoanthra[1,2-b]thiophene-6-ylidene)]dipropanedinitriles, Russ. J. Phys. Chem. A 94, 1936-1942.

84. Uvarov M.N., Plekhanov M.S., Zinoviev V.A., Yanshole V.V., Fedin M.V., Kulik L.V. (2020) Free radicals in organic semiconductors during photooxidation: thin films of polymers P3HT and PCDTBT vs small molecules, DRCN5T and BTR, Chem. Phys. Lett. 754, 137647.

85. Kulik L.V., Uvarov M.N. (2020) Charge photogeneration and Recombination in Ternary Organic Photovoltaic Blend PCDTBT/PC60BM/ICBA Studied by EPR Spectroscopy, Appl. Magn. Res. 51, 1071-1078.

86. Ivanenko A. V., Trashkeev S. I., Vasenin N. T., Nyushkov B. N., Kulik L. V., Nevostruev D. A., Kobtsev S.M. (2020) Generation of optical harmonics in fiber-coupled semiconducting polythiophene films. International Conference Laser Optics (ICLO), Saint Petersburg, 2020, IEEE Xplore, pp. 1-1, doi: 10.1109/ICLO48556.2020.9285822. (Scopus only).

87. Kobeleva E.S., Popov A.A., Baranov D.S., Uvarov M.N., Nevostruev D.A., Degtyarenko K.M., Gadirov R.M., Sukhikh A.S., Kulik L.V. (2021) Origin of poor photovoltaic performance of bis(tetracyanoantrathiophene) non-fullerene acceptor, Chem. Phys. 546, 111162.

88. Zinovieva A. F., Zinovyev V. A., Nenashev A. V., Shklyaev A. A., Kulik L. V., Dvurechenskii A. V. (2021) Electron Spin Resonance in Heterostructures with Ring Molecules of GeSi Quantum Dots, JETP Letters 113, 52–56.

89. Popov A. A., Uvarov M. N., Kulik L.V. (2021) Mode of action of the third component in ternary organic photovoltaic blend PBDB-T/ITIC:PC70BM revealed by EPR spectroscopy, Synth. Met. 277, 116783.

90. Vasenin N.T., Ivanenko A.V., Klement’ev V.M., Kulik L.V., Nevostruev D.A., Nyushkov B.N., Trashkeev S.I., Khomyakov M.N. (2021) High-efficiency generation of harmonics in polythiophene, Quantum Electronics 51, 437 – 445.

91. Gurova O.A., Sysoev, V.I., Lobiak E.V., Makarova A.A., Asanov I.P., Okotrub A.V., Kulik L.V., Bulusheva L.G. (2021) Enhancement of Volumetric Capacitance of Binder-Free Single-Walled Carbon Nanotube Film via Fluorination, Nanomaterials 11, 1135.

92. Kobeleva E. S., Nevostruev D. A., Uvarov M. N., Utkin D. E., Zinoviev V. A., Gurova O. A., Kazantzev M. S., Degtyarenko K. M., Kulikova A. V., Kulik L. V. (2021) Fluorination of single-walled carbon nanotubes and their application in organic photovoltaic cells as an electron acceptor, Russ. Chem. Bull., Int. Ed., 70, 2427—2433. DOI: 10.1007/s11172-021-3363-4

93. Baranov D. S., Nevostruev D. A., Kazantsev M. S., Zinoviev V. A., Zelentsova E. A., Dmitriev A. A., Gritsan N. P., Tsentalovich Y. P., Kotova M., Düreth J., Sperlich A., Dyakonov V., Kulik L. V., (2021) Synthesis, Characterization and Photovoltaic Properties of Electron-Accepting (11-Oxoanthra[2,1-b]thiophen-6-ylidene)dipropanedinitrile-Based Molecules, ChemistrySelect, 6, 6043 –6049.

94. Zinovyev V.A., Zinovieva A. F., Volodin V.A., Gutakovskii A.K., Deryabin A.S., Krupin, A. Yu., Kulik L.V., Zhivulko V.D., Mudryi A.V., Dvurechenskii A.V. (2022) Synthesis of Epitaxial Structures with Two-Dimensional Si Layers Embedded in a CaF2 Dielectric Matrix, JETP Letters 116, 628 – 633.

95. Uvarov M. N., Kobeleva E. S., Degtyarenko K. M., Zinovyev V. A., Popov A. A., Mostovich E. A. Kulik L. V. Fast Recombination of Charge-Transfer State in Organic Photovoltaic Composite of P3HT and Semiconducting Carbon Nanotubes Is the Reason for Its Poor Photovoltaic Performance, Int. J. Mol. Sci. 2023, 24, 4098.

96. Kobeleva E. S., Uvarov M. N., Kravets N. V., Ponomarev S. A., Gurova O. A., Okotrub A. V., Kazantzev M. S., Degtyarenko K. M., Kulik L. V. Fluorinated carbon nanotubes as nonvolatile additive to the active layer of polymer/fullerene solar cells, Fullerenes, Nanotubes and Carbon Nanostructures (2023) DOI: 10.1080/1536383X.2023.2179618